אצטון טכני בריכוז מלא לפוליאסטר

אצטון טכני בריכוז מלא לפוליאסטר

אצטון טכני בריכוז מלא לפוליאסטר דנבר צבעים

אצטון טכני בריכוז מלא לפוליאסטר דנבר צבעים www.denber-paints.co.il

Material Safety Data Sheet

According to 1907/2006/EC, Article 31

Printing date 01/01/2010                                                                                Revision: 11/05/2016

אצטון טכני בריכוז מלא

Identification of the substance/preparation and of the company/undertaking .1

thinner

· Product details

· Trade name: ACETONE

Article number:  918-114

  Application of the substance / the preparation: Diluents.

· Manufacturer/Supplier: DENBER PAINTS & COATINGS ISRAEL LTD..

· Further information obtainable from: Health & Safety

· Information in case of emergency

 2. Hazards identification

Hazard description ::

Xn Harmful

F Highly flammable

 ·: Information concerning particular hazards for human and environment:

The product has to be labeled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version.

R11- Highly flammable.

R36- Irritating to eyes.

R66- Repeated exposure may cause skin dryness or cracking.

R67- Vapors may cause drowsiness and dizziness.

· Classification system:

The classification is according to the latest editions of the EU-lists, and extended by company and literature data.

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3. Composition/information on ingredients

· Chemical characterization

Description: Mixture of substances listed below with nonhazardous additions

Dangerous components:
100%

 

Exposure limits

ACGIH TLV (United States, 2002).

TWA: 500 ppm

TWA: 1188 mg/m3

STEL: 750 ppm

STEL: 1782 mg/m3

OSHA (United States, 2002).

TWA: 750 ppm

TWA: 1800 mg/m3

STEL: 1000 ppm

STEL: 2400 mg/m3

Acetone

CAS: 67-64-1

 

Additional information: for the wording of the listed risk phrases refer to section 16

First aid measures  4.

· General information:

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.

DR

· After inhalation:

Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.

In case of unconsciousness place patient stably in side position for transportation.

· After skin contact: Immediately wash with water and soap and rinse thoroughly.

· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.

· After swallowing: Call for a doctor immediately.

Fire-fighting measures  5.

· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.

· For safety reasons unsuitable extinguishing agents:

Water

Water with full jet

· Protective equipment: Mouth respiratory protective device.

Flammability of the product    :   Flammable.

Auto ignition temperature        :   465°C (869°F)

Flash points                              :   CLOSED CUP: -20°C (-4°F).

Flammable limits                      :   LOWER: 2.6% UPPER: 12.8%

Products of combustion          :   These products are carbon oxides (CO, CO2).

Fire hazards in presence of     :   Extremely flammable in presence of open flames and sparks,                                                                                                                                                                                                                                                                           of heat.

various substances                  :   Flammable in presence of reducing materials.

Slightly flammable to flammable in presence of oxidizing materials, of combustible materials.

Non-flammable in presence of shocks.

Explosion hazards in pr

6. Accidental release measures

· Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.

·: Measures for environmental protection:

Prevent seepage into sewage system, work pits and cellars.

Do not allow to enter sewers/ surface or ground water.

:· Measures for cleaning/collecting:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust)

Dispose contaminated material as waste according to item 13.

Ensure adequate ventilation.

Do not flush with water or aqueous cleansing agents

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 7. Handling and storage

· Handling:

· Information for safe handling:

Ensure good ventilation/exhaustion at the workplace.

Prevent formation of aerosols.

· Information about fire – and explosion protection:

Keep ignition sources away – Do not smoke.

Protect against electrostatic charges.

· Storage:

· Requirements to be met by storerooms and receptacles: Store in a cool location.

· Information about storage in one common storage facility: Not required.

· Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well sealed receptacles.

8. Exposure controls/personal protection

Additional information about design of technical facilities: No further data; see item 7.

 :· Ingredients with limit values that require monitoring at the workplace:
 
100%

 

Exposure limits

ACGIH TLV (United States, 2002).

TWA: 500 ppm

TWA: 1188 mg/m3

STEL: 750 ppm

STEL: 1782 mg/m3

OSHA (United States, 2002).

TWA: 750 ppm

TWA: 1800 mg/m3

STEL: 1000 ppm

STEL: 2400 mg/m3

Acetone CAS: 67-64-1

 

WEL

· Additional information: The lists valid during the making were used as basis.

·: Personal protective equipment:

General protective and hygienic measures ::

Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing

Wash hands before breaks and at the end of work.

Avoid contact with the eyes and skin.

· Respiratory protection:

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.

· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the  degradation

Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application.

· Penetration time of glove material

The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.

· Eye protection:

 

Tightly sealed goggles

 

 9. Physical and chemical properties                                                                                       

· General Information

Form: liquid

Color: transparent

Odor : Pungent. Fruity. Minty. Pleasant. Sweetish. (Strong.)

Taste:  Pungent. Sweetish, astringent. (Strong.)

Molecular weight : 58.08 g/mole

Molecular formula : CH3COCH3

pH (1% soln/water): not available

Boiling/condensation point :  56.2°C (133.2°F)

Melting/freezing point :  -95.35°C (-139.6°F)

Critical temperature: 235 deg C.

Specific gravity : 0.79 (Water = 1)

Vapor pressure : 186.2 mm of Hg (@ 20°C)

Vapor density : 2 (Air = 1)

Volatility : 100% at 21 deg. C.

Odor threshold : 100 ppm

Evaporation rate :  11.6 (Butyl acetate = 1).

Voc :  100%

Viscosity : 0.4 cST @ 20 deg C.

LogKow          : log Kow = 0.58.

Iconicity (in water) : not available

Dispersion properties : See solubility in water, methanol, diethyl ether, n-octanol.

Solubility  : Easily soluble in cold water, hot water, methanol, diethyl ether.

                     Partially soluble in n-octanol

Physical chemical comments : No additional remark.

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 10. Stability and reactivity   

Stability and reactivity      : The product is stable.

Conditions of instability    : Heat, open flames, sparks, static discharge. May react vigorously                              with chloroform in the presence of a base.

Incompatibility with various : Reactive with oxidizing agents, organic peroxides, chromium substances                              trioxide, chromic acid solution potassium tert-butoxide,                                                   hydrogen peroxide, nitric acid and its mixture with sulphuric acid, per monosulphuric acid, chromyl chloride, nitrosyl perchlorate and chloride, bromine, bromine trifluoride, hydrobromites, Sulphur dichloride, dioxygen difluoride, aliphatic amines.

 

Hazardous decomposition products: Carbon monoxide and carbon dioxide may form when heated to decomposition.

Hazardous polymerization : Will not occur. ·

 

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. Toxicological information  11  

Acute toxicity

Toxicity to Animals:    Acute oral toxicity (LD50): 5800 mg/kg [Rat].

                                      Acute dermal toxicity (LD50): 20000 mg/kg [Rabbit].

Acute toxicity of the vapor (LC50): 50100 mg/m3 8 hour(s) [Rat].

Chronic effects on humans: CARCINOGENIC EFFECTS: Classified None. by OSHA, None.                                                                   by NIOSH. A4 (Not classifiable for human or animal.) by ACGIH, D (Not classifiable for human or animal.) by EPA.

                                                 TERATOGENIC EFFECTS: Classified None. for human.

                                     Causes damage to the following organs: kidneys, lungs, the nervous system, liver, upper respiratory tract, skin, eyes.

Other toxic effects on humans: Very hazardous in case of skin contact (permeator), of eye                                                      contact (irritant).

                                       Hazardous in case of skin contact (irritant), of ingestion, of inhalation.

                                     Slightly hazardous in case of skin contact (sensitizer).

Special remarks on toxicity to animals : No additional remark

Special remarks on chronic effects on humans: No additional remark

Special remarks on other toxic effects on humans: Material is irritating to mucous                                                                                                      membranes and upper respiratory tract.

 12. Ecological information

Eco toxicity   :   Eco toxicity in water: 5540 mg/l, 96 hours [Trout]. 5000 mg/l, 24 hours [Goldfish].                    8300 mg/l, 96 hours [Bluegill sunfish]. 2100 mg/l, 24 hours [shrimp]. 10 mg/l, 48 hours [Daphnia].

BOD and COD : BOD5: 1.52 p/p.

                           BOD: 70.9 % in 28 days, CO2 Evolution Test (Modified Sturm OECD 301B) and                                                      the EU C.4-C. (In-house results).

Biodegradable/OECD :    Biodegradable from OECD.

Mobility    :     Not available

Products of degradation: Possibly hazardous short term degradation products are not likely.                              However, long term degradation products may arise. carbon oxides (CO, CO2)

 

Toxicity of the products of biodegradation: The products of degradation are non-toxic.

Special remarks on the products of biodegradation:   No additional remark.

 

 13. Disposal considerations                                                                                                      Product Recommendation :

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

·Uncleaned packaging:

·Recommendation: Disposal must be made according to official regulations.

Waste information: Waste must be disposed of in accordance with federal, state and local                                                    environmental control regulations

Waste stream  : RCRA Hazardous Waste: F003, RQ is 5000 lbs.

14. Transport information
Regulatory

information

UN

number

Proper shipping name Class Packing

group

Label Additional

information

DOT

Classification

UN1090 ACETONE D O T C L A S S 3 :

Flammable liquid.

II reportable

Quantity

5000 lbs. (2268 kg)

TDG

Classification

UN1090 ACETONE T D G C L A S S 3 :

Flammable liquid.

II Special Provisions

0 9 9 N o t

a c c e p t a b l e

f o r

t r a n s p o r t b y

passenger ship.

IMDG Class UN1090 ACETONE

 

C l a s s 3 . 1 :

Flammable liquid

II
IATA-DGR

CLASS

UN1090 ACETONE Class 3: Flammable

liquid.

II
15. Regulatory information                                                                                                      

HCS classification   : HCS CLASS: Flammable liquid having a flash point lower than 37.8°C                              (100°F).

U.S. Federal regulations : TSCA 5(e) substance consent order: Dimethylketone

TSCA 8(a) IUR: Dimethylketone

TSCA 8(b) inventory: Dimethylketone

TSCA 12(b) one time export: Dimethylketone

SARA 302/304/311/312 extremely hazardous substances: No                            products were found.

SARA 302/304 emergency planning and notification: No products                were found.

SARA 302/304/311/312 hazardous chemicals: No products were  found.

SARA 311/312 MSDS distribution – chemical inventory – hazard identification: No products were found.

SARA 313 toxic chemical notification and release reporting: No products were found.

Clean Water Act (CWA) 307: No products were found.

Clean Water Act (CWA) 311: No products were found.

Clean air act (CAA) 112 accidental release prevention: No products were found.

Clean air act (CAA) 112 regulated flammable substances: No products were found.

Clean air act (CAA) 112 regulated toxic substances: No products were found.

State regulations  :      Rhode Island RTK hazardous substances: Dimethylketone

Pennsylvania RTK: Dimethylketone: (environmental hazard)

Florida: Dimethylketone

Minnesota: Dimethylketone

Massachusetts RTK: Dimethylketone

New Jersey: Dimethylketone

New Jersey spill list: Dimethylketone

California prop. 65: No products were found.

 

EU Regulations

      Hazard symbol(s)

Classification :              Highly flammable        Irritant

Risk phrases  :   

R11- Highly flammable.

R36- Irritating to eyes.

R66- Repeated exposure may cause skin dryness or cracking.

R67- Vapors may cause drowsiness and dizziness.

Safety phrases :

S9- Keep container in a well-ventilated place.

S16- Keep away from sources of ignition – No smoking.

S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

EINECS Number :  200-662-2.

16. Other information

3

National Fire                                                                           fire hazard

Protection Association                        

1

0

(U.S.A.)

                                                           health                                      reactivity

 

Specific hazard

 

References :   -Material safety data sheet emitted by: la Commission de la Santé et de la Sécurité du Travail du Québec.

-The Sigma-Aldrich Library of Chemical Safety Data, Edition II.

-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987.

– LOLI Database: The regulated Chemicals List of Lists.

– CHEMINFO: Canadian Centre for Occupational Health and Safety, Issue: 97-3 (August, 1997).-

BDH; Hazard Data Disk, Version 3.- CESARS: Chemical Evaluation and Retrieval System, Produced by: Ontario Ministry of Environment and Michigan Department of Natural Resouces, Issue:97-3 (August, 1997).- TOMES Plus System: Toxicology, Occupational Medicine & Environmental Series:

incorporating:- MEDITEX, HAZARDTEXT, 1st Medical Response Protocols, INFOTEXT, HSDB, CHRIS,

OHM/TADS, IRIS, NIOSH Pocket Guide, RTECS, NJ Fact Sheets, North American Emergency

Response Guides, REPROTEXT, REPROTOX, TERIS, Shepard's Catalog of Teratogenic Agents.

Other special considerations : No additional remark.

 

This information is based on our present knowledge. However, this shall not constitute a guarantee for any  specific product features and shall not establish a legally valid contractual relationship.

· Department issuing MSDS: Denber paints and coatings Ltd.- Health & Safety Department.

Contact:

Dr. Blen Evgenia

Phone: +972(8)9960794

Fax: +972(8)9960649

e-mail: denber@bezeqint.net

 

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